I havent read all these replys so here goes:
Volkswagen have cxalled their 4WD Syncro and 4Motion. The systems are used on all VAG cars but but under the brand name. I.E a 3B Passat uses the Audi Quattro system but its badged as a 4Motion on the later cars and Syncro on the earlier ones.
Golf and A3 use the Haldex clutch system, again Quattro in the Audi and 4Motion in the VW.
So to answer your question I guess its possible on the Audi swstem by removing the drive shafts at the front. The VW system I did see a mod that would switch the cars priority, so instead of it putting drive to the front and use the rear when needed it will do the reverse.